RESISTIVITY AND LOW FREQUENCY NOISE OF HYBRID COMPOSITES WITH CARBON NANOTUBES AND CARBONIZED NICKEL

Frydrichas Mireckas1, Sandra Pralgauskaitė1, Jan Macutkevič1

1 Institute of Applied Electrodynamics and Telecommunications, Faculty of Physics, Vilnius University, Lithuania

[email protected]

Carbon nanoparticle composites have garnered notable scientific and industrial interest due to a wide range of filler particle options and their corresponding electrical, thermal, and mechanical properties. However, agglomeration of filler particles remains a crucial technological consideration for the applicability of these materials, as it depends on the type and amount of fillers [1].

Low frequency noise measurement enables the investigation of electrical characteristics, as well as the quality of composite materials, since a greater presence of structural defects typically results in higher noise level [2]. For applications in electronics, 1/\(f\) noise is particularly significant due to the limit it imposes on the sensitivity and selectivity of electrical sensors [3].

Resistivity and low frequency (10 Hz – 20 kHz) noise characteristics of hybrid epoxy composites with multi-walled carbon nanotubes (MWCNTs) and carbonized nickel (Ni@C) were investigated at room temperature and in the temperature range of (75–365) K. Composites were prepared via dispersion of epoxy and different concentrations of MWCNTs (0, 0.09 vol.%) and Ni@C (0, 0.025, 0.2, 5, 15, 25, and 30 vol.%).

Figure 1
Fig. 1. (a) Resistivity dependence on voltage; (b) voltage noise spectral density dependence on voltage (room temperature, 86 Hz).
The resistivity of the composites is almost independent of voltage (Fig. 1a). Lowest resistivity is observed in composites with 30 vol.% and 15 vol.% Ni@C. In contrast, the 25 vol.% Ni@C composite resistivity is much higher than other single-filler composites. This could be due to increased agglomeration in this composite. The resistivity of hybrid MWCNT/Ni@C composites is generally determined by the MWCNT content and shows no clear dependence on Ni@C concentration.

Low frequency noise spectra are primarily of 1/\(f\) type. In the proportionality of voltage fluctuation spectral density to voltage \(S_{U} \sim U^{b}\), exponent \(b\) is close to 1 for most of the studied composite samples. This is indicative of an increased contribution of tunneling processes to the conductivity in the composite (Fig. 1b).


[1] V. Choudhary et al., Carbon nanotubes and their composites (Syntheses and Applications of Carbon Nanotubes and Their Composites, IntechOpen, 2013)

[2] S. Pralgauskaitė et al., Resistivity and low-frequency noise characteristics of epoxy-carbon composites (Journal of Applied Physics, vol. 121(11), 2017

[3] A.A. Balandin, Low-frequency 1/f noise in graphene devices (Nature Nanotechnology, vol. 8(8), 2013)