A CASE STUDY OF EXTENSIVE BIOMASS BURNING RELATED BLACK CARBON EMISSIONS DURING MIDSUMMER EVE IN VILNIUS, LITHUANIA

Agnė Minderytė1, Kamilė Kandrotaitė1, 2, Audrė Kalinauskaitė1, Lina Davulienė1, Lucja Janicka3, Vadimas Dudoitis1, Iwona S. Stachlewska3, Steigvilė Byčenkienė1

1 Department of Environmental Research, Center for Physical Sciences and Technology, Vilnius, Lithuania

2 Faculty of Physics, Vilnius university, Lithuania

3 Institute of Geophysics, Faculty of Physics, University of Warsaw

[email protected]

Aerosol particles can scatter or absorb light depending on their chemical composition. Meanwhile, the chemical composition is highly dependent on the source [1]. It is widely known that sulphate and nitrate contribute significantly to light scattering. Even though there are numerous studies on aerosol particles originating from biomass burning, a consensus on the strength of the radiative effect of the aerosols has not been reached [2]. The case study investigates the impact of an extensive nationwide bonfire-burning event, associated with the celebration of Midsummer, on the aerosol black carbon (BC) mass concentration and optical properties at an urban background site. Aerosol BC mass concentration was measured using an Aethalometer (AE33, Magee Scientific); aerosol scattering properties were recorded using a Nephelometer (TSI model 3563); the aerosol particle number size distribution was evaluated using a condensation particle counter (CPC, TSI model 3085) and a differential mobility analyzer (DMA, TSI model 3085). The changes in aerosol BC source contribution, light absorption coefficient, absorption and scattering Ångström exponents (AAE and SAE, respectively), single scattering albedo (SSA), and particle number size distribution were analyzed during the period from 1st to 30th June 2022. The Midsummer celebration took place on the night of 23rd June when a 3-fold increase in the total BC mass concentration was observed. Moreover, the extensive bonfire burning resulted in a 7-fold increase in BCBB (BC originated from biomass burning) level compared to the monthly average value. The high contribution of BCBB to the total aerosol BC appears to increase aerosol light absorption. Thus, it performs a warming role in the atmosphere as the SSA value decreased to 0.62. This multi-parameter investigation focuses on the high pollution event when biomass-burning aerosols originated nationwide in a rather short time scale. The results provide a better perception of the biomass-burning-related aerosol characteristics in the ambient atmosphere and their impact on atmospheric radiative transfer.

Figure 1
Fig. 1. Scatter plot of aerosol SSA and SAE together with BCBB contribution to BCTotal.

[1] C. D.Cappa, K. R. Kolesar, X. Zhang et al., Understanding the optical properties of ambient sub- and supermicron particulate matter: results from the CARES 2010 field study in northern California, Atmospheric Chemistry and Physics, 16, 6511–6535 (2016).

[2] V. Masson-Delmotte, P. Zhai, A. Pirani, S. L. Connors, C. Péan et al., IPCC 2021. Climate Change 2021: The physical science basis. Contribution of Working Group I to the sixth assessment report of the intergovernmental panel on climate change (2021).