FEMTOSECOND LASER 3D MICROFABRICATION OF ELASTOMERIC RESIN

Giedrė Grigalevičiūtė1, Linas Jonušauskas1, 2, Mangirdas Malinauskas1

1 Laser Research Center, Faculty of Physics, Vilnius University, Lithuania

2 Femtika Ltd., Vilnius, Lithuania

[email protected]

The polymerization initiated by light is already successfully used and applied in such areas as laboratories research as well as industry. The main idea of 3D direct laser writing is simple and rapid way to fabricate 3D solid polymeric objects out of liquid prepolymer, consisting monomers, oligomers and photoinitiators. Employing femtosecond laser lithography true 3D, with intricate internal geometry, micro- or nano-scaled structures in high quality can be manufactured [1]. The applications of photopolymerization are shown in such fields as medicine, micro- and fiber optics, photonics, micro-mechanics. [2]

Despite the fact, that 3D laser lithography can be used as a versatile tool, there is a lack of elastomeric photosensitive materials that could be polymerized for specific applications. In this work femtosecond laser lithography experiments were performed with elastomeric resin UV-PDMS (manufacturer ShinEtsu Japan). During the experiments the goal was to determine the optimal parameters for the micro-fabrication of the aforementioned material. The 3D structures shown in the Figure 1 were fabricated with varied parameters and dosages by the change of laser beam average power, scanning (velocity, number and direction). The optimal parameters for achievements of quality results were while using the objective of 63x magnification and 1.4 numerical aperture, the power from 0.4 mW to 0.6 mW and the fabrication velocity up to 3000 μm/s. Also there was noticed, that the scanning in different directions (opposite and the same) results in different symmetry of the fabricated object (Fig. 2). This can be explained by the diffusion of generated radicals and heat [3].

Figure 1
Fig. 1. The CAD model of fabricated structures during the experiment, on the left: the view from the top; on the right – the view from the side.
Figure 2
Fig. 2. The structures fabricated of UV-PDMS elastomer in different conditions: (a) the scanning directions are opposite, (b) the scanning directions are the same.

Based on the optimized fabrication parameters, the sample microporous 3D scaffold structures for cell growth will be presented validating the applicability of the chosen material and fabrication technology.


[1] M. Malinauskas et al, Ultrafast laser processing of materials: from science to industry, Light. Sci. Appl. 5(e16133) (2016).

[2] A. Ovsianikov et al, Photonic and Biomedical Applications of the Two-Photon Polymerization Technique, Stereolithography Materials, Processes and Applications, 257-299, Springer, New York (2011).

[3] Y. Li et al, Uniform suspended nanorods fabricated by bididrectional scanning via two-photon photopolymerization, Nanotechnology 19 375304 (2008).